AI Article Synopsis
- Mixed-metal reagents, specifically [NaMg(CH2SiMe3)3] (1) and [(THF)NaMg(NPh2)3(THF)] [3-(THF)(2)], can function as precatalysts in chemical reactions.
- These precatalysts facilitate hydroamination and trimerization of isocyanates (RNCO), a type of compound containing the isocyanate functional group.
- The effectiveness of these reactions is influenced by the steric bulk of the substituent (R) attached to the isocyanate.
Article Abstract
Mixed-metal reagents [NaMg(CH2SiMe3)3] (1) and [(THF)NaMg(NPh2)3(THF)] [3-(THF)(2)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.
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| http://dx.doi.org/10.1039/c3cc45167d | DOI Listing |
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