The newly prepared complex [Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.
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| http://dx.doi.org/10.1021/jo401492n | DOI Listing |
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