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Synthesis of an imidazolium phosphanide zwitterion and its conversion into anionic imidazol-2-ylidene derivatives. | LitMetric
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Synthesis of an imidazolium phosphanide zwitterion and its conversion into anionic imidazol-2-ylidene derivatives.

Paresh K Majhi Gregor Schnakenburg Zsolt Kelemen Laszlo Nyulaszi Derek P Gates Rainer Streubel

Angew Chem Int Ed Engl

Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany) http://anorganik.chemie.uni-bonn.de/akstreubel.

Published: September 2013

Matter of opinion: The novel zwitterion 1 has been synthesized and studied theoretically and also converted into anionic NHCs 2. The former can also be described as a phosphinidene adduct of an abnormal N-heterocyclic carbene (1') and, in the same vein, the latter represents a phosphinidene adduct of an anionic N-heterocyclic dicarbene (2').

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http://dx.doi.org/10.1002/anie.201304431DOI Listing

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