This paper reports a new technique that combines the features of Accumulative Roll Bonding (ARB) and Asymmetric Rolling (AR). This technique has been developed to enable production of ultra-thin bimetallic foils. Initially, 1.5 mm thick AA1050 and AA6061 foils were roll-bonded using ARB at 200°C, with 50% reduction. The resulting 1.5 mm bimetallic foil was subsequently thinned to 0.04 mm through four AR passes at room temperature. The speed ratio between the upper and lower AR rolls was 1:1.3. The tensile strength of the bimetallic foil was seen to increase with reduction in thickness. The ductility of the foil was seen to reduce upon decreasing the foil thickness from 1.5 mm to 0.14 mm, but increase upon further reduction in thickness from 0.14 mm to 0.04 mm. The grain size was about 140 nm for the AA6061 layer and 235 nm for the AA1050 layer, after the third AR pass.
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http://dx.doi.org/10.1038/srep02373 | DOI Listing |
Faraday Discuss
August 2022
Diamond Light Source, Harwell Campus, Didcot, UK.
Palladium and palladium-platinum foils were analysed using temperature-programmed near-ambient pressure X-ray photoelectron spectroscopy (TP-NAP-XPS) under methane oxidation conditions. Oxidation of palladium is inhibited by the presence of water, and in oxygen-poor environments. Pt addition further inhibits oxidation of palladium across all reaction conditions, preserving metallic palladium to higher temperatures.
View Article and Find Full Text PDFRSC Adv
July 2021
Joint Center for Artificial Photosynthesis, Materials Sciences Division and Chemical Sciences Division, Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Among metals used for CO electroreduction in water, Cu appears to be unique in its ability to produce C2+ products like ethylene. Bimetallic combinations of Cu with other metals have been investigated with the goal of steering selectivity creating a tandem pathway through the CO intermediate or by changing the surface electronic structure. Here, we demonstrate a facile cation exchange method to synthesize Ag/Cu electrocatalysts for CO reduction using Cu sulfides as a growth template.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2022
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China.
The introduction of tin (Sn) into Zn-based catalyst can change its intrinsic properties of the electrochemically reduction of CO to CO, obtaining a high formate yield. The electron transfer from Zn to Sn lowers down the d-band center of Sn, leading to a more reliable surface adsorption of the *OCHO intermediate and high formate selectivity. The obtained ZnSn catalyst enables formate formation with a drastically boosted Faradaic efficiency (FE) up to 94%, which is 2.
View Article and Find Full Text PDFSensors (Basel)
June 2018
Univ Lyon, INSA-Lyon, LGEF, EA682, F-69621 Villeurbanne, France.
A thermal energy harvester based on a double transduction mechanism and which converts thermal energy into electrical energy by means of piezoelectric membranes and bimetals, has previously been developed and widely presented in the literature In such a device, the thermo-mechanical conversion is ensured by a bimetal whereas the electro-mechanical conversion is generated by a piezoelectric ceramic. However, it has been shown that only 19% of the mechanical energy delivered by the bimetal during its snap is converted into electrical energy. To extract more energy from the bimetallic strip and to increase the transduction efficiency, a new way to couple piezoelectric materials with bimetals has thus been explored through direct deposition of piezoelectric layers on bimetals.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2017
Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Electrochemical water splitting is an important process to produce hydrogen and oxygen for energy storage and conversion devices. However, it is often restricted by the oxygen evolution reaction (OER) due to its sluggish kinetics. To overcome the problem, precious metal oxide-based electrocatalysts, such as RuO and IrO, are widely used.
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