Furfural production by 'acidic steam stripping' of lignocellulose.

ChemSusChem

Shell Chemicals Europe B.V. Weena 70, 3012 CM Rotterdam (The Netherlands).

Published: November 2013

Furfural and acetic acid are produced with approximately 60 and 90 mol % yield, respectively, upon stripping bagasse with a gaseous stream of HCl/steam and condensing the effluent to water/furfural/acetic acid. The reaction kinetics is 1(st)  order in furfural and 0.5(th)  order in HCl. A process concept with full recycling of the reaction effluents is proposed to reduce the energy demand to <10 tonsteam  tonfurfural (-1) and facilitate the product recovery through a simple liquid/liquid separation of the condensate into a water-rich and a furfural-rich phase.

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Source
http://dx.doi.org/10.1002/cssc.201300234DOI Listing

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