Planets form in the disks around young stars. Their formation efficiency and composition are intimately linked to the protoplanetary disk locations of "snow lines" of abundant volatiles. We present chemical imaging of the carbon monoxide (CO) snow line in the disk around TW Hya, an analog of the solar nebula, using high spatial and spectral resolution Atacama Large Millimeter/Submillimeter Array observations of diazenylium (N2H(+)), a reactive ion present in large abundance only where CO is frozen out. The N2H(+) emission is distributed in a large ring, with an inner radius that matches CO snow line model predictions. The extracted CO snow line radius of ~30 astronomical units helps to assess models of the formation dynamics of the solar system, when combined with measurements of the bulk composition of planets and comets.
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http://dx.doi.org/10.1126/science.1239560 | DOI Listing |
Phys Chem Chem Phys
December 2024
Department of Chemistry, Virginia Commonwealth University, Richmond, VA 23284-2006, USA.
Benzonitrile molecules are present in ionizing environments including interstellar clouds and solar nebulae, where their ions can form adducts with neutral molecules such as acrylonitrile leading to the formation of a variety of nitrogen-containing complex organics. Herein, we report on the formation of complex organics by the sequential reactions of 1-4 acrylonitrile (CNH) molecules with the benzonitrile radical cation (CNH˙). The results reveal the formation of the covalently bonded -acrylonitrile-benzonitrile radical cation (CNH˙) with a rate coefficient of 2.
View Article and Find Full Text PDFJ Phys Chem Lett
November 2024
Department of Chemistry, Virginia Commonwealth University, Richmond, Virginia 23284-2006, United States.
J Phys Chem A
July 2024
School of Science, Engineering and Technology, Pennsylvania State University─Harrisburg, 777 W. Harrisburg Pike, Middletown, Pennsylvania 17057, United States.
One of the first minerals to condense from the early solar nebula was hibonite (CaAlO), demonstrating a hexagonal crystal structure. There are five unique aluminum cation sites (M1-M5) in hibonite. Although hibonite contains aluminum, it can also have 3d transitional metals that substitute at aluminum cation sites, such as titanium, and other metals such as magnesium.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
June 2024
Department of Earth, Planetary and Space Sciences, University of California, Los Angeles, CA 90095-1567.
Magmatic iron-meteorite parent bodies are the earliest planetesimals in the Solar System, and they preserve information about conditions and planet-forming processes in the solar nebula. In this study, we include comprehensive elemental compositions and fractional-crystallization modeling for iron meteorites from the cores of five differentiated asteroids from the inner Solar System. Together with previous results of metallic cores from the outer Solar System, we conclude that asteroidal cores from the outer Solar System have smaller sizes, elevated siderophile-element abundances, and simpler crystallization processes than those from the inner Solar System.
View Article and Find Full Text PDFiScience
May 2024
Virtual Muography Institute, Global, Tokyo, Japan.
Evidence of hot and cold igneous processes has been reported in small satellites and dwarf planets of the Solar System. Olivine and pyroxenes were detected in the spectral bands of both small satellites and dwarf planets. The aqueously altered form of olivine and serpentine has been detected in the spectrums of Ceres and Miranda hinting at possible hydrothermal processes in their interiors.
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