Ionic conductivity of [Li+@C60](PF6(-)) in organic solvents and its electrochemical reduction to Li+@C60(·-).

Chem Commun (Camb)

Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Published: August 2013

The ionic conductivity of [Li(+)@C60](PF6(-)) was measured in o-dichlorobenzene, and found to be higher than that of TBA(+)PF6(-). Electrochemical reduction of [Li(+)@C60](PF6(-)) without any supporting electrolyte gave the monovalent radical anion Li(+)@C60˙(-), as confirmed by the characteristic ESR signal and NIR absorption band.

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Source
http://dx.doi.org/10.1039/c3cc43901aDOI Listing

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