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An exceptionally high boron content supramolecular cuboctahedron. | LitMetric

An exceptionally high boron content supramolecular cuboctahedron.

Chem Commun (Camb)

Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.

Published: December 2013

AI Article Synopsis

  • A new supramolecular cuboctahedron made of 240 boron atoms has been created using a method called coordination-driven assembly.
  • The structure consists of copper paddle-wheel nodes combined with carborane-isophthalic acids, resulting in a simple and high-purity synthesis.
  • Its precise characterization through X-ray diffraction sets it apart from other boron-rich nanostructures, highlighting its unique properties.

Article Abstract

A boron-rich supramolecular cuboctahedron containing an impressive 240 boron atoms has been synthesized via coordination-driven assembly. The cuboctahedron, which is composed of Cu(2+) paddle-wheel nodes and carborane-isophthalic acids, was obtained simply and in high purity. The ability to precisely characterize the nanostructure via X-ray diffraction makes it unique among boron-rich nanostructures.

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Source
http://dx.doi.org/10.1039/c3cc44173cDOI Listing

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