Cation location in microporous zeolite, SSZ-13, probed with xenon adsorption measurement and 129Xe NMR spectrum.

J Nanosci Nanotechnol

Clean Energy Technology Laboratory and Department of Applied Chemical Engineering, Chonnam National University, Gwangju 500-757, Korea.

Published: June 2013

The location of metal ion, Ag2+, Ca2+, Cu2+ and Y3+ in the SSZ-13 has been investigated with xenon adsorption measurement and 129Xe NMR spectrum. It was referred that the location of the metal ion varies depending on the corresponding charge. The ion-exchanged Ag ion was located in the alpha-cage to interact directly with xenon. Others multivalent cation contributed little with xenon because these were present near the six membered rings where xenon cannot access.

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http://dx.doi.org/10.1166/jnn.2013.7019DOI Listing

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