We present herein a novel method to prepare free-standing Dried Foam Films (DFFs) whereby individual polynuclear manganese complexes cover quantitatively the holes of micro-grids; the fabricated, homogeneous films have a cross-sectional thickness of only ca. 5 nm and are characterised by high mechanical stability.
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http://dx.doi.org/10.1039/c3cc42954g | DOI Listing |
Molecules
November 2024
Department of Functional Materials and Hydrogen Technology, Faculty of Advanced Technologies and Chemistry, Military University of Technology, 2 Kaliskiego Street, 00908 Warsaw, Poland.
ACS Appl Mater Interfaces
January 2025
Neurotherapeutics Laboratory, Department of Pharmaceutical Engineering and Technology, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005, India.
Herein, we unveil a remarkable finding for synthesizing room-temperature-stable, nontoxic, ultrasmall free-standing diamond cubic tin nanocrystals (α-Sn) with beta forms in the aqueous phase, avoiding conventional approaches that typically use toxic elements or large reactive substrates (Si/InSb) to stabilize α-Sn above 13 °C. Herein, for the first time, we demonstrate the successful synthesis of free-standing alpha tin with extraordinary stability up to 80 °C and in the aqueous phase at room temperature, which was supported by powder X-ray diffraction and X-ray photoelectron spectroscopy characterization methods. This synthetic approach eliminates the need to use hazardous materials, bulky substrates, and elevated temperatures, offering a safer, low-cost, and more sustainable alternative.
View Article and Find Full Text PDFChemistry
November 2024
Flinders Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Adelaide, SA 5042, Australia.
We have developed a rapid and facile method for preparing free-standing nanocomposite of gold nanoparticles with graphene oxide (Au@GO) in water under continuous flow in the absence of harsh reducing agents and any other auxiliary substances, as a method with favourable green chemistry metrics. This uses a vortex fluidic device (VFD) where induced mechanical energy and photo-contact electrification associated with the dynamic thin film in the rapidly rotating tube tilted at 45° while simultaneously UV irradiated (λ=254 nm, 20 W) results in decomposition of water to hydrogen and hydrogen peroxide with growth of the gold nanoparticles on the surface of the GO. We have established that the resulting Au@GO composite sheets rapidly catalyse the degradation of commercial dyes like methyl orange (MO) and methylene blue (MB) using the hydrogen peroxide generated in situ in the VFD.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
Applied Chemistry and Materials Department, Leitat Technological Centre, C/Innovació, 2, 08225 Terrassa, Spain.
High-performance and cost-efficient electrocatalysts and electrodes are needed to improve the hydrogen evolution reaction (HER) for the hydrogen (H) generation in electrolysers, including microbial electrolysis cells (MECs). In this study, free-standing carbon nanofiber (CNF) films with supported cobalt phosphide nanoparticles have been prepared by means of an up-scalable electrospinning process followed by a thermal treatment under controlled conditions. The produced cobalt phosphide-supported CNF films show to be nanoporous (pore volume up to 0.
View Article and Find Full Text PDFSmall
January 2025
School of Materials Science and Engineering, Peking University, Beijing, 100871, China.
Sodium metal is a promising anode material for energy storage beyond lithium-ion batteries due to its abundance and low cost. However, the uncontrolled growth of dendrites and associated safety concerns have limited the practical application of sodium metal batteries (SMBs). By embedding nucleophilic tin seeds in a free-standing carbon film (FSF), here, an effective solution is developed to stabilize the sodium metal anode.
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