The inclusion of volatile derivatives of benzene and cyclohexane in β-cyclodextrin (β-CD), hydroxypropyl-β-CD, and hydrophilic β-CD-thioethers was investigated by static headspace gas chromatography (HS-GC) and molecular modelling. The obtained binding constants strongly increase with the amount of space filling of the CD cavity and the salt concentration. β-CD thioethers show a 3-10 times higher binding potential than native β-CD.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701372 | PMC |
| http://dx.doi.org/10.3762/bjoc.9.133 | DOI Listing |
Publication Analysis
Top Keywords
space filling
8
filling β-cyclodextrin
4
β-cyclodextrin β-cyclodextrin
4
β-cyclodextrin derivatives
4
derivatives volatile
4
volatile hydrophobic
4
hydrophobic guests
4
guests inclusion
4
inclusion volatile
4
volatile derivatives
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!