Predicting transient inflow rates into a tunnel is an important issue faced by hydrogeologists. Most existing analytical solutions overestimate the initial discharge due to the assumption that drilling was instantaneous over the entire tunnel length. In addition, they assume a homogeneous system. An alternative model was recently developed for tunnels intersecting heterogeneous formations, but its application was reduced to the case of confined flow to deep tunnels in weakly diffusive aquifers. In this paper, we adapt existing analytical solutions for drainage systems to the specific case of a tunnel progressively drilled in a highly diffusive heterogeneous unconfined aquifer. The case of a tunnel overlying an impervious layer is analytically solved by applying the superposition principle, while the case of a tunnel constructed some distance above an impervious layer is solved by discretizing the tunnel length into subsectors. Both models can simulate transient discharge into a tunnel drilled at various speeds through a heterogeneous unconfined aquifer, and allow the prediction of discharge rates in shallow tunnels located in highly diffusive aquifers. We successfully applied this approach to a tunnel in heterogeneous volcanic rock.
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http://dx.doi.org/10.1111/gwat.12087 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China.
Nanoconfinement at the interface of heterogeneous Fenton-like catalysts offers promising avenues for advancing oxidation processes in water purification. Herein, we introduce a template-free strategy for synthesizing nanoconfined catalysts from municipal sludge (S-NCCs), specifically engineered to optimize reactive oxygen species (ROS) generation and utilization for rapid pollutant degradation. Using selective hydrofluoric acid corrosion, we create an architecture that confines atomically dispersed Fe centers within a micro-mesoporous carbon matrix in situ.
View Article and Find Full Text PDFWater Res
March 2025
GNS Science, New Zealand.
Source protection zone delineation has evolved over the past decades from fixed radius or analytical and numerical methods which do not consider uncertainty, to more complex stochastic numerical approaches. In this paper we explore options for delineating a source protection zone, while considering the inherent uncertainty involved in characterizing hydraulic conductivity. We consider a representative pumping well in an unconfined alluvial aquifer under steady-state flow conditions, with the hydraulic conductivity distribution inferred from borehole lithology data in the West Melton area near Christchurch, New Zealand.
View Article and Find Full Text PDFJ Contam Hydrol
November 2024
Indian Institute of Technology Guwahati, Guwahati, Assam, India 781039. Electronic address:
Source identification of a contaminant has always been challenging for accurately modeling groundwater transport. Source identification problems are classified into several parts, such as identifying the location of contamination, the strength of contamination, the time the contaminant is introduced into the groundwater, and the duration of its activity. Identifying the sources considering all the parts as variables increases the computational complexity.
View Article and Find Full Text PDFSci Total Environ
December 2024
Key Laboratory of Groundwater Conservation of MWR & School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing 100083, PR China; State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences (Beijing), Beijing 100083, PR China. Electronic address:
JACS Au
July 2024
Catalytic Processes and Materials Group, Faculty of Science and Technology, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, Enschede 7500 AE, The Netherlands.
Enzymes can precisely control the speed and selectivity of chemical reactions by modifying locally the solvent-reactant interactions. To extrapolate these attributes to heterogeneous catalysts, we have employed thermoresponsive poly -isopropylacrylamide (-NIPAM) brushes bonded to silica spheres containing palladium. These polymers can form hydrogen bonds with water molecules at low temperatures (<32 °C) allowing the polymer to stay swollen.
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