WO3 deposition from tungsten ethoxide precursor solutions at room temperature is demonstrated. The W(OEt)6 precursor can be converted under inert conditions and hence avoids sample contamination with oxygen, opening a pathway to more stable devices. The stoichiometry of all WO3 layers and the optoelectronic performance of the respective SMOLEDs well match thermally evaporated WO3 and its corresponding SMOLEDs. The solution processed WO3 hole injection layers enable the fabrication of blue phosphorescent OLEDs with low onset voltage and current efficiencies of up to 14 cd A(-1) .
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http://dx.doi.org/10.1002/adma.201301627 | DOI Listing |
Materials (Basel)
January 2025
College of Physics and Electronic Information, Shandong Key Laboratory of Biophysics, Dezhou University, Dezhou 253023, China.
Electrochromic capacitors, which are capable of altering their appearances in line with their charged states, are drawing substantial attention from both academia and industry. Tungsten oxide is usually used as an electrochromic layer material for electrochromic devices, or as an active material for high-performance capacitor electrodes. Despite this, acceptable visual aesthetics in electrochromic capacitors have almost never been achieved using tungsten oxide, because, in its pure form, this compound only displays a onefold color modulation from transparent to blue.
View Article and Find Full Text PDFMolecules
December 2024
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.
Catalyzing hydrogen evolution reaction (HER) is a key process in high-efficiency proton exchange membrane water electrolysis (PEMWE) devices. To replace the use of Pt-based HER catalyst, tungsten carbide (WC) is one of the most promising non-noble-metal-based catalysts with low cost, replicable catalytic performance, and durability. However, the preparation access to scalable production of WC catalysts is inevitable.
View Article and Find Full Text PDFRadiat Environ Biophys
January 2025
Department of Physics, Yazd University, Yazd, Iran.
Polymer nanocomposites have been investigated as lightweight and suitable alternatives to lead-based clothing. The present study aims to fabricate flexible, lead-free, X-ray-shielding composites using a polyvinyl chloride (PVC) matrix and different nanostructures. Four different nanostructures containing impure tungsten oxide, tungsten oxide (WO), barium tungstate (BaWO), and bismuth tungstate (BiWO) were synthesized through various methods.
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Electronic Thin Films and Integrated Devices, National Engineering Research Center of Electromagnetic Radiation Control Materials, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of China, Chengdu, 610054, P. R. China.
Dual-band tungsten oxide (WO) electrochromic films are extensively investigated, yet challenges persist regarding complex fabrication processes and limited cyclic stability. In this paper, a novel approach to prepare graphdiyne quantum dots (GDQDs) doped WO films with a hexagonal crystal structure, is presented. Structural characterization reveals that the GDQDs/WO possesses a coral-like, loose structure with high crystallinity due to the synergistic modulation of morphology and crystallinity.
View Article and Find Full Text PDFMicromachines (Basel)
December 2024
College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China.
This study introduces the development of a W-M electrochromic film, characterized by a "coral"-like TiO@WO heterostructure, synthesized via a hydrothermal process leveraging the inherent instability of MXene. The film showcases exceptional electrochromic performance, with a coloring response time of 2.8 s, a bleaching response time of 4.
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