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Enantioselective total syntheses of pygmaeocins B and C. | LitMetric
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Enantioselective total syntheses of pygmaeocins B and C.

Akiko Obase Akihito Kageyama Yuki Manabe Tsukasa Ozawa Takaaki Araki Hiromasa Yokoe Makoto Kanematsu Masahiro Yoshida Kozo Shishido

Org Lett

Graduate School of Pharmaceutical Sciences, The University of Tokushima, 1-78-1 Sho-machi, Tokushima, 770-8505, Japan.

Published: July 2013

The first enantioselective total syntheses of pygmaeocins B and C have been accomplished using an efficient and highly diastereoselective intramolecular Heck cyclization for the construction of a quaternary stereogenic center and the functionalized A-ring of the natural products as the key step.

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 Source
http://dx.doi.org/10.1021/ol401543bDOI Listing

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