(Adipato-κ(2) O,O')di-aqua-[bis-(pyridin-2-yl-κN)amine]-cobalt(II) trihydrate.

Acta Crystallogr Sect E Struct Rep Online

Département de Technologie, Faculté de Technologie, Université 20 Août 1955 de Skikda, 21000 Skikda, Algeria ; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine I, 25000 Constantine, Algeria.

Published: June 2013

In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octa-hedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate di-pyridyldi-amine ligand, two O-atom donors from one of the carboxyl-ate groups of the bidentate chelating adipate ligand and two water mol-ecules. In addition, there are three solvent water mol-ecules which are involved in both intra- and inter-unit O-H⋯O hydrogen-bonding inter-actions, which together with an amine-water N-H⋯O hydrogen bond produce a three-dimensional framework.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684895PMC
http://dx.doi.org/10.1107/S1600536813012981DOI Listing

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