Background: The anomalous properties of water have been of great interest for generations of scientists. However the impact of small amount of deuterium content which is always present in water has never been explored before. For the first time the fundamental properties of deuterium depleted (light) water at 4°C and 20°C are here presented.
Results: The obtained results show the important role of the deuterium in the properties of bulk water. At 4°C the lowest value of the kinematic viscosity (1.46 mm2/s) has been found for 96.5 ppm D/H ratio. The significant deviation in surface tension values has been observed in deuterium depleted water samples at the both temperature regimes. The experimental data provides direct evidence that density, surface tension and viscosity anomalies of water are caused by the presence of variable concentration of deuterium which leads to the formation of water clusters of different size and quantity.
Conclusions: The investigated properties of light water reveal the origin of the water anomalies. The new theoretical model of cluster formation with account of isotope effect is proposed.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3703265 | PMC |
http://dx.doi.org/10.1186/1752-153X-7-103 | DOI Listing |
Sci Rep
December 2024
Physical Geography, Institute of Geography, Technical University Dresden, Dresden, Germany.
It is generally accepted that a weakening of the North Atlantic thermohaline circulation caused the Younger Dryas cooling. Although the role of seasonality was emphasized previously, this aspect is rarely considered yet, and it remains elusive how this impacted hydroclimate during winters and summers across Central Europe. Here, we coupled biomarker-based δO and δH from Bergsee in southern Germany to reconstruct deuterium excess as a proxy for evaporation history from the Bølling-Allerød to the Preboreal.
View Article and Find Full Text PDFPlants (Basel)
November 2024
Department of Molecular Biology and Radiobiology, Faculty of AgriSciences, Mendel University in Brno, 61300 Brno, Czech Republic.
Heavy water (DO) is scarce in nature, and despite its physical similarity to water, DO disrupts cellular function due to the isotope effect. While microbes can survive in nearly pure DO, eukaryotes such as are more sensitive and are unable to survive higher concentrations of DO. To explore the underlying molecular mechanisms for these differences, we conducted a comparative proteomic analysis of , , and after 180 min of growth in a DO-supplemented media.
View Article and Find Full Text PDFMetabolomics
October 2024
Deutenomics Science Institute, Los Angeles, CA, USA.
Small
December 2024
Key Laboratory of Plateau Oxygen and Living Environment of Tibet Autonomous Region, College of Science, Tibet University, Lhasa, 850000, P. R. China.
RSC Sustain
October 2024
Institute of Materials Chemistry, TU Wien Getreidemarkt 9/BC 1060 Vienna Austria
Carbon dioxide (CO) and carbon monoxide (CO) hydrogenation to methane (CH) or methanol (MeOH) is a promising pathway to reduce CO emissions and to mitigate dependence on rapidly depleting fossil fuels. Along these lines, a series of catalysts comprising copper (Cu) or palladium (Pd) nanoparticles (NPs) supported on zinc oxide (ZnO) as well as bimetallic CuPd NPs supported on ZnO or graphene were synthesized various methodologies. The prepared catalysts underwent comprehensive characterization high-resolution transmission electron microscopy (HRTEM), energy-dispersive X-ray spectroscopy (EDX) mapping, electron energy loss spectroscopy (EELS), X-ray diffraction (XRD), hydrogen temperature-programmed reduction and desorption (H-TPR and H-TPD), and deuterium temperature-programmed desorption (DO-TPD).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!