The reaction of the Tc(I) complex [Tc(NO)Cl(HOMe)(PPh)] with stoichiometric amounts of 2-mercatopyridine and a proton scavenger yields [Tc(NO)Cl(Spy)(PPh)] or [Tc(NO)(Spy)(PPh)], depending upon quantities of ligands employed. These two complexes have been structurally characterized. The small bite angles of the bidentate mercaptopyridine ligands cause significant deviation from octahedral coordination geometry.
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| http://dx.doi.org/10.1016/j.ica.2010.09.025 | DOI Listing |
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