Preparation of triethylene-tetramine grafted magnetic chitosan for adsorption of Pb(II) ion from aqueous solutions.

J Hazard Mater

State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China.

Published: September 2013

In this paper, a novel triethylene-tetramine grafted magnetic chitosan was synthesized. The chemical structure and the percentage content of each element of chitosan and its derivatives were characterized by elemental analysis, infrared spectroscopy, solid state (13)C NMR, X-ray diffraction analysis and thermogravimetric analysis, respectively. Their surface topography was observed by the transmission electron microscope. The results of adsorption kinetics and adsorption thermodynamics showed the adsorption mechanism could be better described by the pseudo-second-order equation (R>0.999). The adsorption isotherm was well fitted by the Langmuir equation (R>0.999), and 0

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http://dx.doi.org/10.1016/j.jhazmat.2013.05.019DOI Listing

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