We report a synthetic nickel complex containing proton relays, [Ni(P(Ph)2N(C6H4OH)2)2](BF4)2 (P(Ph)2N(C6H4OH)2 = 1,5-bis(p-hydroxyphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclo-octane), that catalyzes the production of H2 in aqueous acetonitrile with turnover frequencies of 750-170,000 s(-1) at experimentally determined overpotentials of 310-470 mV.
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| http://dx.doi.org/10.1039/c3cc43203c | DOI Listing |
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