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Bent thorocene complexes with the cyanide, azide and hydride ligands. | LitMetric

Bent thorocene complexes with the cyanide, azide and hydride ligands.

Chem Commun (Camb)

CEA, IRAMIS, SIS2M, CNRS UMR 3299, CEA/Saclay, 91191 Gif-sur-Yvette, France.

Published: July 2013

Reaction of the linear thorocene with NC(-), N3(-) and H(-) led to the bent derivatives [(Cot)2Th(X)](-) (X = CN, N3) and the bimetallic [{(Cot)2Th}2(μ-H)](-), whereas only [(Cot)2U(CN)](-) could be formed from (Cot)2U.

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Source
http://dx.doi.org/10.1039/c3cc42763cDOI Listing

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