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Structural isomerism leading to variable proton conductivity in indium(III) isophthalic acid based frameworks. | LitMetric

Structural isomerism leading to variable proton conductivity in indium(III) isophthalic acid based frameworks.

Chem Commun (Camb)

Physical/Materials Chemistry Division, CSIR National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008, India.

Published: July 2013

AI Article Synopsis

  • Two versions of In(III)-isophthalate based metal-organic frameworks (MOFs) were studied for their proton conductivity.
  • In-IA-2D-1 shows higher conductivity (3.4 × 10(-3) S cm(-1)) but only in very humid conditions (98% relative humidity).
  • In-IA-2D-2 conducts protons (2.6 × 10(-5) S cm(-1)) in both humid and dry environments.

Article Abstract

Proton conductivity has been studied thoroughly in two isomeric In(III)-isophthalate based MOFs. In-IA-2D-1 is capable of showing proton conductivity (3.4 × 10(-3) S cm(-1)) under humidified conditions (98% RH), whereas In-IA-2D-2 can conduct protons (2.6 × 10(-5) S cm(-1)) under humidified as well as anhydrous conditions.

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Source
http://dx.doi.org/10.1039/c3cc41939hDOI Listing

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