Naphthoxanthenyl, a new stable phenalenyl type radical stabilized by electronic effects.

Org Lett

WestCHEM, School of Chemistry, University of Glasgow , Joseph-Black-Building, University Avenue, Glasgow G12 8QQ, United Kingdom, and Grup d'Enginyeria Molecular, Institut Químic de Sarrià, Universitat Ramon Llull, E-08017 Barcelona, Spain.

Published: June 2013

Naphthoxanthenyl 1 is a new stable phenalenyl-type radical. Electrochemical studies indicate that 1 has two reversible redox processes that occur on comparatively short time scales. Crystals containing 1 can be grown by electrocrystallization, suggesting that they are conductive.

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Source
http://dx.doi.org/10.1021/ol401117gDOI Listing

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