7-Methyl-1-phenyl-1,10-di-hydro-pyrazolo-[3,4-a]carbazole.

Acta Crystallogr Sect E Struct Rep Online

Postgraduate Research Department of Physics, Rajah Serfoji Government College (Autonomous), Thanjavur 613 005, Tamilnadu, India.

Published: May 2013

In the title mol-ecule, C20H15N3, the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In the crystal, mol-ecules are linked via N-H⋯N hydrogen bonds, forming an infinite chain along [010]. Mol-ecules are further linked by nine π-π [centroid-centroid distances vary from 3.6864 (11) to 3.9802 (11) Å] and one C-H⋯π inter-action, forming a three-dimensional network.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648322PMC
http://dx.doi.org/10.1107/S1600536813010994DOI Listing

Publication Analysis

Top Keywords

mol-ecules linked
8
7-methyl-1-phenyl-110-di-hydro-pyrazolo-[34-a]carbazole title
4
title mol-ecule
4
mol-ecule c20h15n3
4
c20h15n3 atoms
4
atoms carbazole
4
carbazole unit
4
unit deviate
4
deviate planarity
4
planarity [maximum
4

Similar Publications

4-Bromo-,'-di-phenyl-benzimidamide '-oxide.

IUCrdata

October 2024

Département de Chimie, Université de Montréal, Complexe des sciences, 1375, Avenue Thérèse-Lavoie-Roux, Montréal, Québec H2V 0B3, Canada.

The title compound, CHBrNO, crystallizes with two similar mol-ecules in the asymmetric unit. The extended structure features dimers linked by pairs of N-H⋯O and C-H⋯O hydrogen bonds. The HNCNO moiety of the title compound shows delocalization over the N-C-N part, as evidenced by the similar C-N bond distances.

View Article and Find Full Text PDF

In the title compound, CHNO, the piperazine-2,3-dione ring adopts a half-chair conformation. In the crystal, the mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming (010) sheets.

View Article and Find Full Text PDF

In the crystal of the title compound, CHN, the mol-ecules are linked by N-H⋯N hydrogen bonds, generating a (4) chain extending along the -axis direction. One of the ethyl groups is disordered over two sets of sites with a refined occupancy ratio of 0.582 (15):0.

View Article and Find Full Text PDF

The mol-ecule of the title compound, [Ni(CHO)(CHN)(HO)]·CHOH, has triclinic () symmetry. This compound is of inter-est for its anti-microbial properties. The asymmetric unit comprises two independent complex mol-ecules, which are linked by N-H⋯O and O-H⋯O hydrogen bonds along [111].

View Article and Find Full Text PDF

Synthesis, crystal structure and properties of μ-tetra-thio-anti-monato-bis-[(cyclam)zinc(II)] perchlorate 0.8-hydrate.

Acta Crystallogr E Crystallogr Commun

October 2024

Institut für Anorganische Chemie, Universität Kiel, Max-Eyth.-Str. 2, D-24118 Kiel, Germany.

The reaction of Zn(ClO)·6HO with NaSbS·9HO in a water/aceto-nitrile mixture leads to the formation of the title compound, (μ-tetra-thio-anti-monato-κ :')bis-[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ )zinc(II)] perchlorate 0.8-hydrate, [Zn(SbS)(CHN)]ClO·0.8HO or [(Zn-cyclam)(SbS)][ClO]·0.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!