In the mol-ecule of the title compound, C28H22F2O4, the benzoyl groups are aligned almost anti-parallel and the fluorobenzene rings form a dihedral angle of 14.12 (7)°. The dihedral angles between the 2,7-dieth-oxy-naphthalene ring system and the benzene rings are 70.00 (4) and 67.28 (4)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯F hydrogen bonds, forming layers parallel to the ab plane. The layers are further connected by π-π inter-actions [centroid-centroid distances of 3.6115 (10) Å] into a three-dimensional structure.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647838 | PMC |
| http://dx.doi.org/10.1107/S1600536813008295 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Ethyl 4-[(2-hy-droxy-eth-yl)amino]-2-(4-meth-oxyphen-yl)-1-methyl-5-oxo-2,5-di-hydro-1-pyrrole-3-carboxyl-ate.
IUCrdata
December 2024
EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, United Kingdom.
In the title compound, CHNO the pyrrolidine ring is almost planar and subtends a dihedral angle of 85.77 (7)° with the pendant phenyl ring. An intra-molecular N-H⋯O hydrogen bond generates an (6) loop.
View Article and Find Full Text PDFSynthesis and crystal structure of -10-(4-cyano-phen-yl)-10,11,22,23-tetra-hydro-9,21-5,8:15,12-bis-(metheno)[1,5,11]tri-aza-cyclo-hexadecino[1,16-:5,6-']di-indole di-chloro-methane monosolvate.
Acta Crystallogr E Crystallogr Commun
January 2025
Osaka Research Institute of Industrial Science and Technology, 1-6-50 Morinomiya, Joto-ku, Osaka 536-8553, Japan.
The asymmetric unit of the title compound is composed of one host mol-ecule, -4-(1 ,5 -3-aza-1,5(3,9)-dicarbazola-cyclo-octa-phane-3-yl)benzo-nitrile and one di-chloro-methane solvate mol-ecule, CHN·CHCl. The host mol-ecule possesses a planar chirality but crystallizes as a racemate in the space group 2/. It adopts an -configuration, in which two carbazole rings are partially overlapped with a parallel orientation.
View Article and Find Full Text PDFCrystal structure of -xylene@silicalite-1.
Acta Crystallogr E Crystallogr Commun
January 2025
School of Chemical and Biological Engineering, Seoul National University, 1, Gwanak-ro, Gwanak-gu, Seoul 08826, South Korea.
The crystal structure of a highly loaded complex of silicalite-1 (SL-1) with eight mol-ecules of -xylene per unit cell has been solved by single-crystal X-ray diffraction. In the crystal, four symmetrical SiO·2CH subunits per unit cell are observed. The -xylene mol-ecules sit at two different positions within the SL-1 channels.
View Article and Find Full Text PDFCrystal structure of luliconazole.
Acta Crystallogr E Crystallogr Commun
January 2025
University of Lodz Faculty of Chemistry Pomorska 163/165 90-236 Łódź Poland.
The crystal structure of luliconazole {LCZ; CHClNS; systematic name: ()-[(4)-4-(2,4-di-chloro-phen-yl)-1,3-di-thio-lan-2-yl-idene](1-imidazol-1-yl)aceto-nitrile} is reported. In the mol-ecule of the title compound, the di-thiol-ane ring adopts an envelope conformation, while the di-chloro-phenyl ring exhibits disorder. In the crystal packing of luliconazole, only two inter-molecular C-H⋯N hydrogen bonds are observed.
View Article and Find Full Text PDFCrystal structure and Hirshfeld surface analysis of the chalcone derivative (2)-3-[4-(di-phenyl-amino)phen-yl]-1-[4-(prop-1-yn-2-yl-oxy)phen-yl]prop-2-en-1-one.
Acta Crystallogr E Crystallogr Commun
January 2025
Department of Biotechnology SRM Institute of Science and Technology, Kattankulathur Campus Chengalpattu Tamil Nadu - 603203 India.
In the crystal structure of the title chalcone derivative, CHNO, the mol-ecule adopts an s- conformation with respect to the C=O and C=C bonds. The tri-phenyl-amine moiety has a propeller-type shape, with dihedral angles between the mean planes of pairs of phenyl rings of 72.1 (6), 69.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!