rac-(1S*,4aS*,8aS*)-4a-Hy-droxy-2-methyl-perhydro-spiro-[isoquinoline-4,1'-cyclo-hexa-n]-2'-one.

Acta Crystallogr Sect E Struct Rep Online

Institut National Polytechnique Félix Houphouët-Boigny, Enseignant-Chercheur à l'INP-HB de Yamoussoukro, BP 991 Yamoussoukro, Côte d'Ivoire.

Published: May 2013

In the title compound, C15H25NO2, all three six-membered rings adopt chair conformations. The cyclo-hexane and piperidine rings within the perhydro-isoquinoline are trans-trans fused. The N atom has a trigonal-pyramidal geometry (the sum of the bond angles is 328.0°). The methyl substituent occupies the sterically preferrable equatorial position. In the crystal, mol-ecules form infinite [100] chains via O-H⋯N hydrogen bonds.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647829PMC
http://dx.doi.org/10.1107/S1600536813007010DOI Listing

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