The nonlinear Huygens-Fresnel principle has been used to design multifunctional nonlinear optical devices. Focused second-harmonic generations have been observed with strong polarization sensitivity. Numerical simulations have been performed, and the results fit well with the experiments.
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http://dx.doi.org/10.1364/OL.38.001793 | DOI Listing |
ACS Nano
January 2025
Sauvage Laboratory for Smart Materials, School of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China.
With the potential to surpass the Shockley-Queisser (S-Q) limitation for solar energy conversion, the bulk photovoltaic (BPV) effect, which is induced by the broken inversion symmetry of the lattice, presents prospects for future light-harvesting technologies. However, the development of BPV is largely limited by the low solar spectrum conversion efficiency of existing noncentrosymmetric materials with wide band gaps. This study reports that the strain-induced reduction of inversion symmetry can enhance the second-order nonlinear susceptibility (χ) of SnPSe crystals by an order of magnitude, which contributes to an extremely high value of 1.
View Article and Find Full Text PDFChem Sci
December 2024
Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology Tianjin 300384 China
Non-centrosymmetric (NCS) compounds can exhibit many symmetry-dependent functional properties, yet their rational structure design remains a great challenge. Herein, a strategy to introduce F-centered octahedra to construct a perovskite-type framework filled by π-conjugated [BO] dimers is proposed to obtain NCS compounds. The first examples of antiperovskite or double antiperovskite borate fluorides, [(M/Ba)Ca]F[BO] (M = K, Rb) and [CsBaCa]F[BO], have been successfully designed and synthesized.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Physics and Materials Science, Changji University, Changji 831100, People's Republic of China.
Finding novel efficient nonlinear optical materials with large second-order nonlinearity for the UV spectral range remains a formidable challenge, especially for silicate systems. Using a high-temperature solid reaction in a tight vacuum environment, two ultraviolet nonlinear optical materials with a moderate second harmonic generation (SHG) response have been created: PbSiOC and PbCaSiO. The SHG values they computed are roughly 2.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, P. R. China.
Organic-inorganic hybrid lead halides have been extensively studied due to their outstanding physical properties and diverse compositional elements. However, environmentally benign tin-based hybrids with remarkable flexibility in bandgap engineering have been less investigated. Herein, we report the successful design and synthesis of three tin-based organic-inorganic hybrid compounds through precise molecular modification: [Me(i-Pr)N][SnBr] (), [MeCHCl(i-Pr)N][SnBr] (), and [MeCHBr(i-Pr-Br)N][SnBr] ().
View Article and Find Full Text PDFACS Nano
January 2025
Center for High Pressure Science (CHiPS), State Key Laboratory of Metastable Materials Science & Technology, Yanshan University, Qinhuangdao 066004, China.
Moiré superlattices, created by stacking different van der Waals materials at twist angles, have emerged as a versatile platform for exploring intriguing phenomena such as topological properties, superconductivity, the quantum anomalous Hall effect, and the unconventional Stark effect. Additionally, the formation of moiré superlattice potential can generate spontaneous symmetry breaking, leading to an anisotropic optical response and electronic transport behavior. Herein, we propose a two-step chemical vapor deposition (CVD) strategy for synthesizing WS/SbS moiré superlattices.
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