The potential biotoxicity to the environment should be addressed during wastewater treatment. In this study, biotoxicity of coking wastewater effluent from MBR, Fenton, electro-Fenton and coagulation treatment processes was evaluated using embryos and larvae of Japanese medaka (Oryzias latipes). The acute toxicity based on 96-h larval mortality as well as the chronic toxicity based on embryo hatching, larvae swim-up failure, growth, and sexual ratio were determined. The results showed that different treatment processes have various biotoxicity levels. The acute toxicity of Fenton and electro-Fenton effluents was much higher than that of MBR and coagulation. For the chronic toxicity, the effluent of the Fenton/electro-Fenton process displayed lower embryo hatching, larvae survival and growth in comparison with the effluents of MBR and coagulation. No endocrine disruption was detected in MBR, Fenton and electro-Fenton effluents, but was contained in the coagulation effluent. The biotoxicity test indicated that the effluent of MBR was very safe for the environment. The toxicological indices were necessary for ecological safety maintenance in the industrial wastewater treatment.
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http://dx.doi.org/10.1039/c3em00064h | DOI Listing |
Chemosphere
December 2024
São Carlos Institute of Chemistry, University of São Paulo, Avenida Trabalhador São Carlense, 400, São Carlos, 13566-590, Brazil. Electronic address:
The present work investigated the application of UVC combined with electrogenerated HO (UVC/e-HO) for BTA degradation using a Printex L6 carbon-based (PL6C) gas diffusion electrode (GDE). The studies were carried out by analyzing the influence of the current density, pH and initial BTA concentration in the contaminant degradation process. Under optimal conditions using 0.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
School of Life Sciences, Key Laboratory of Jiangxi Province for Functional Biology and Pollution Control in Red Soil Regions, Jinggangshan University, Ji'an 343009, PR China. Electronic address:
Anodic oxidation (AO) has been extensively hailed as a robust and promising technology for pollutant degradation, but the parasitic formation of oxychlorides (ClO) would induce a seriously over-evaluated electrochemical COD removal performance and dramatical biotoxicity increasement of the AO-treated Cl-laden effluents. Herein, we shed new light on the roles of HO high-efficiently electrogenerated in three-dimensional (3D) reactor in inhibiting ClO production and promoting pollutant degradation, which has been overlooked in previous literature. Total yield of ClO in phenol simulated wastewater containing 30 mM Cl was dropped from 25 mM and 24.
View Article and Find Full Text PDFWater Res
December 2024
Instituto de Energías Renovables, Universidad Nacional Autónoma de México (IER-UNAM). Priv. Xochicalco S/N, Col. Centro, Temixco, Morelos, 62580, Mexico.
The Electro-Fenton process (EF) has been conventionally applied to efficiently degrade refractory and/or toxic pollutants. However, in this work, EF was used as a reverse engineering tool to selectively synthesize highly value-added products (oxalic or oxamic acid) through the degradation of the model pollutant acetaminophen, a widely used analgesic and antipyretic drug. It was found that the production of either oxalic or oxamic acid is dictated by the applied current density.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Ecological Civilization, Hainan University, No. 58 Renmin Road, Haikou 570228, China; State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130021, China.
Electrochemically upcycling polyvinyl chloride (PVC) into high-value small molecules represents a sustainable strategy for mitigating plastic pollution. Herein, a cost-effective self-supporting electrode with abundant vacancies, i.e.
View Article and Find Full Text PDFEnviron Res
December 2024
Department of Environmental Engineering, Beijing University of Technology, Beijing, 100124, PR China; National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology, Beijing University of Technology, Beijing, 100124, PR China. Electronic address:
To enhance the contaminant removal efficiency of the electro-Fenton (E-Fenton) process, a nitrogen and phosphorus co-doped graphite felt (NPGF) cathode was synthesized using an anodic oxidation technique. An ascorbic acid-coupled NPGF E-Fenton system was then established for the degradation of ciprofloxacin (CIP). The NPGF cathode featured abundant oxygen-containing functional groups (such as -COOH and -OH), which enhanced the selectivity of oxygen reduction and facilitated the formation of HO.
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