Anomalous Schottky specific heat and structural distortion in ferromagnetic PrAl2.

Phys Rev Lett

The Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, Iowa 50011-3020, USA.

Published: May 2013

Unique from other rare earth dialuminides, PrAl(2) undergoes a cubic to tetragonal distortion below T = 30 K in a zero magnetic field, but the system recovers its cubic symmetry upon the application of an external magnetic field of 10 kOe via a lifting of the 4f crystal field splitting. The nuclear Schottky specific heat in PrAl(2) is anomalously high compared to that of pure Pr metal. First principles calculations reveal that the 4f crystal field splitting in the tetragonally distorted phase of PrAl(2) underpins the observed unusual low temperature phenomena.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevLett.110.186405DOI Listing

Publication Analysis

Top Keywords

schottky specific
8
specific heat
8
magnetic field
8
crystal field
8
field splitting
8
anomalous schottky
4
heat structural
4
structural distortion
4
distortion ferromagnetic
4
pral2
4

Similar Publications

A first-principles study of SOF and SOF adsorption onto PdSe-based monolayers: Favorable sensitivity and selectivity by doping single Cu or Rh atom.

Environ Res

January 2025

College of Artificial Intelligence, Southwest University, Chongqing, 400715, China; Hubei Engineering Research Center for Safety Monitoring of New Energy and Power Grid Equipment, Hubei University of Technology, Wuhan, 430068, China. Electronic address:

In this first-principles study, we simulate the adsorption of SOF and SOF molecules on the pristine, Cu- and Rh-doped PdSe monolayer, in order to explore their potentials as novel gas sensors for status evaluation of the SF-insulation devices. Single Cu or Rh atom is doped by the replacement of a Se atom within the PdSe surface, with the formation energy of 0.40 and -0.

View Article and Find Full Text PDF

Dipole-induced transitions from Schottky to Ohmic contact at Janus MoSiGeN/metal interfaces.

Nanoscale Horiz

January 2025

SEU-FEI Nano-Pico Center, Key Laboratory of MEMS of Ministry of Education, Southeast University, Nanjing 210096, China.

Janus MoSiGeN monolayers exhibit exceptional mechanical stability and high electron mobility, which make them a promising channel candidate for field-effect transistors (FETs). However, the high Schottky barrier at the contact interface would limit the carrier injection efficiency and degrade device performance. Herein, using density functional theory calculations and machine learning methods, we investigated the interfacial properties of the Janus MoSiGeN monolayer and metal electrode contacts.

View Article and Find Full Text PDF

GaO Schottky photodiodes are being actively explored for solar-blind ultraviolet (SBUV) detection, owing to the fast photoresponse and easy fabrication. However, their performance, limited by the Schottky contact, mostly underperforms the expectations. Herein, a Ni/β-GaO vertical Schottky barrier diode (SBD) with an ultrathin anode electrode is demonstrated.

View Article and Find Full Text PDF

Two-dimensional (2D) hexagonal boron nitride (hBN) has garnered significant attention due to its exceptional thermal and chemical stability, excellent dielectric properties, and unique optical characteristics, making it widely used in deep ultraviolet (DUV) applications. However, the integration of hBN with plasmonic materials in the visible region (532 nm) has not been fully explored, particularly in terms of morphology regulation and size control of mono- and bimetallic nanoparticles (BMNPs) namely gold (Au), silver (Ag) and Au-Ag. A Schottky junction-based metal-semiconductor contact configuration is employed to achieve hot-carrier reflections on the metal side, enhancing the quantum efficiency of the photodetector.

View Article and Find Full Text PDF

Photocatalytic technology holds significant promise for sustainable development and environmental protection due to its ability to utilize renewable energy sources and degrade pollutants efficiently. In this study, BiOI nanosheets (NSs) were synthesized using a simple water bath method with varying amounts of mannitol and reaction temperatures to investigate their structural, morphological, photoelectronic, and photocatalytic properties. Notably, the introduction of mannitol played a critical role in inducing a transition in BiOI from an n-type to a p-type semiconductor, as evidenced by Mott-Schottky (M-S) and band structure analyses.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!