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Palladium-catalyzed C-H arylation using phosphoramidate as a directing group at room temperature. | LitMetric

Palladium-catalyzed C-H arylation using phosphoramidate as a directing group at room temperature.

Org Lett

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

Published: June 2013

This communication describes the first phosphoramidate directing group for synthetically useful arylation. Remarkably, the nature of a new directing group drives selective C-H bond activation to afford diverse N-aryl phosphoramidates in good to excellent yields at room temperature.

Download full-text PDF

Source
http://dx.doi.org/10.1021/ol4009987DOI Listing

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