Efficient epoxidation of olefins by H2O2 catalyzed by iron "helmet" phthalocyanines.

Chem Commun (Camb)

Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, CNRS-Université Lyon 1, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France.

Published: June 2013

High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2-2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.

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Source
http://dx.doi.org/10.1039/c3cc42301hDOI Listing

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