AI Article Synopsis
- Researchers created fluorescent pyrimidine analogs that include a fused biphenyl unit, achieving high yields through specific chemical reactions.
- The synthesis involved stereoselective N-glycosylation and Suzuki-Miyaura cross-coupling methods to build the desired compounds.
- The resulting "push-pull" fluorophores show strong changes in their emission properties based on the solvent used, due to twisted intramolecular charge-transfer states.
Article Abstract
Fluorescent pyrimidine analogs containing a fused biphenyl unit were prepared in high yields using stereoselective N-glycosylation and Suzuki-Miyaura cross-coupling reactions. The resulting "push-pull" fluorophores exhibit highly solvatochromic emissions from twisted intramolecular charge-transfer (TICT) states.
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| http://dx.doi.org/10.1021/ol400930s | DOI Listing |
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