Efficient C-H/C-N and C-H/C-CO-N conversion via decatungstate-photoinduced alkylation of diisopropyl azodicarboxylate.

Org Lett

Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan, and PhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.

Published: May 2013

Tetrabutylammonium decatungstate (TBADT) accelerated the addition of C-H bonds to the N═N double bond of diisopropyl azodicarboxylate (DIAD) under irradiation conditions. The photoinduced three-component coupling between cyclic alkanes, CO, and DIAD was also achieved to give the corresponding acyl hydrazides.

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Source
http://dx.doi.org/10.1021/ol401061vDOI Listing

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