A catalytic transfer hydrogenation process was developed for the production of γ-valerolactone (GVL) from ethyl levulinate (EL) and a H-donor at room temperature. Ethyl levulinate was almost quantitatively converted to γ-valerolactone. Further, a two step process for producing GVL from biomass derived platform molecules was also reported.
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http://dx.doi.org/10.1039/c3cc40980e | DOI Listing |
Chem Commun (Camb)
January 2025
Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan Provincial Center for Research & Development of Natural Products, School of Pharmacy, Yunnan University, Kunming, 650091, P. R. China.
In recent years, visible light-induced ligand-to-metal charge transfer (LMCT) has emerged as an attractive approach for synthesizing a range of functionalized molecules. Compared to conventional photoredox reactions, photoinduced LMCT activation does not depend on redox potential and offers diverse reaction pathways, making it particularly suitable for the activation of inert bonds and the functional modification of complex organic molecules. This review highlights the indispensable role of photoinduced LMCT in synthetic chemistry, with a focus on recent advancements in LMCT-mediated hydrogen atom transfer (HAT), C-C bond cleavage, decarboxylative transformations, and radical ligand transfer (RLT) reactions.
View Article and Find Full Text PDFACS Nano
January 2025
Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 9190401, Israel.
Semiconductor-metal hybrid nanoparticles (HNPs) are promising materials for photocatalytic applications, such as water splitting for green hydrogen generation. While most studies have focused on Cd containing HNPs, the realization of actual applications will require environmentally compatible systems. Using heavy-metal free ZnSe-Au HNPs as a model, we investigate the dependence of their functionality and efficiency on the cocatalyst metal domain characteristics ranging from the single-atom catalyst (SAC) regime to metal-tipped systems.
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Bio-Fibers and Eco-Textiles, College of Materials Science and Engineering, College of Environmental Science and Engineering, Qingdao University, Qingdao, 266071, P. R. China.
Hydrogen spillover-based binary (HSBB) system has attracted significant attention in alkaline hydrogen evolution reaction (HER). Accelerating hydrogen spillover in the HSBB system is crucial for the HER activity. Herein, a highly efficient HSBB system is developed by anchoring nano-Ru on oxygen vacancy (Vo) rich amorphous/crystal ZrO.
View Article and Find Full Text PDFNanoscale Adv
December 2024
Center for Advanced Chemistry, Institute of Research and Development, Duy Tan University Danang 550000 Vietnam
Electrolytic glucose oxidation has garnered great interest in energy-saving hydrogen generation. However, high charge-transfer resistance and inefficient active centers have been recognized as the primary issues for poor electrochemical performance. In this study, for the first time, we offer a novel defect-rich CeO /β-Ni(OH) composite nanosheet-decorated Ni foam electrocatalyst (denoted as Ce@NF-GA), synthesized a unique hydrothermal approach under the co-participation of glycerol and acetic acid.
View Article and Find Full Text PDFRSC Adv
January 2025
Department of Chemistry and Biochemistry, Thapar Institute of Engineering and Technology Patiala-147004 Punjab India
In this study, a detailed DFT investigation was conducted to systematically analyze the scavenging activity of six hydrazone compounds (1-6) against HOO˙ and CHOO˙ radicals. Three mechanistic pathways were explored: hydrogen atom transfer (HAT), single electron transfer followed by proton transfer (SETPT), and sequential proton loss electron transfer (SPLET). These mechanisms were evaluated based on thermodynamic parameters, including bond dissociation enthalpy (BDE), ionization potential (IP), proton dissociation enthalpy (PDE), proton affinity (PA), and electron transfer enthalpy (ETE) in the gas phase, water, and pentyl ethanoate.
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