In recent years, wastewater treatment, especially for wastewaters which are not suitably recycled by conventional or normal biological processes, is getting more importance. Of late, natural biopolymer based flocculants are extensively used for wastewater treatment because of low cost, environment-friendly and easily availablility from reproducible farm and forest resources. This article introduces the development of a natural polymer based flocculant [amylopectin grafted with poly (acrylic acid) - AP-g-PAA] for treatment of synthetic effluent as well as mining industry wastewater. The graft copolymer based flocculants have been developed under optimum conditions and characterized using viscometry, (13)C NMR, SEM, TGA, rheological characteristics, determination of hydrodynamic radius and CHN analysis. The flocculation characteristics of grafted and ungrafted polysaccharide have been evaluated in synthetic effluents (as Fe-ore, kaolin, Mn ore suspensions) as well as in mining industry wastewater.
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http://dx.doi.org/10.1016/j.carbpol.2013.03.025 | DOI Listing |
Int J Biol Macromol
January 2025
Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China; State Key Laboratory of Efficient Production of Forest Resources, Beijing Forestry University, Beijing 100083, China. Electronic address:
Due to the emphasis on the environmental and health issues caused by petroleum-based plastics, renewable lignocellulosic materials emerge as promising substitutes. However, their practical application remains hindered by unsatisfactory properties such as fragility and sensitivity to water. Dealing with the challenge of non-thermal processing of xylan and addressing the issue of performance degradation resulting from the hygroscopicity of materials.
View Article and Find Full Text PDFLangmuir
January 2025
Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Bio-functional Materials, Department of Materials Science and Engineering, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, P. R. China.
Steric stabilization and lubrication give loop polymer brushes enhanced antifouling properties. In the study, linear zwitterionic poly(NMASMCMS) brushes were first constructed on a poly(ethylene terephthalate) (PET) surface through surface-initiated reversible addition-fragmentation chain-transfer (SI-RAFT) polymerization. The tethered linear brushes on sheets were then thiolated with ethanolamine, followed by oxidation to form loop brushes.
View Article and Find Full Text PDFLangmuir
January 2025
School of Chemistry and Chemical Engineering, Jiangsu Province Hi-Tech Key Laboratory for Biomedical Research, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
Int J Biol Macromol
December 2024
College of Food Science and Engineering, Inner Mongolia Agricultural University, 306 Zhaowuda Road, Hohhot, Inner Mongolia 010018, China. Electronic address:
Chilled beef is a perishable food product. Due to the broad-spectrum antimicrobial properties of chitosan, and the biodegradability of PLLA, chitosan and PLLA are introduced double bonding groups to obtain Chitosan-graft-Glycidyl methacrylate (Cs-g-GMA) and Poly(L-lactic acid)-co-poly(butylene itaconate) (PLBI), respectively. Cs-g-GMA is then grafted onto the surface of PLBI films by UV curing to produce PLBI/Cs-g-GMA films with non-migratory, broad-spectrum antimicrobial, biodegradable, and possess good oxygen barrier properties, compared to current antimicrobial films.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu Province, China. Electronic address:
Over the past decades, emerging bioplastics have attracted much interest from the scientific and industrial communities because of public concerns about environmental problems and sustainable development. In this study, poly(lactic acid) (PLA) was toughened by ductile biodegradable poly(butylene adipate-co-terephthalate) (PBAT) and biosourced plasticizer epoxidized linseed oil (ELO), and a chain-extending agent (CEA) was added to promote the compatibility and toughness of the bio-blends. It was shown that "in situ" grafted polymers were created in the bio-blends with the aid of CEA, greatly enhancing the compatibility and ductility of the compatibilized blends.
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