Low-temperature synthesis and nanomagnetism of large-area alpha-Fe2O3 nanobelts.

J Nanosci Nanotechnol

School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, PR China.

Published: February 2013

AI Article Synopsis

  • Large-area 1D alpha-Fe2O3 nanostructures were successfully grown on iron substrates using a low-temperature thermal oxidation process without a catalyst.
  • Characterization confirmed these structures are single crystalline, and two types—nanobelts and nanoflakes—formed due to variations in growth temperatures.
  • The study also noted that the Morin temperature for these nanostructures is significantly lower than in bulk material, with coercive field values changing based on temperature.

Article Abstract

Large-area one dimensional (1D) alpha-Fe2O3 nanostructures were grown on iron substrates by catalyst-free thermal oxidation process at low temperatures in air. The structure characterization revealed that the nanostructures are single crystalline alpha-Fe2O3. Two kinds of alpha-Fe2O3 nanostructures, nanobelts and nanoflakes, were obtained due to the different growth temperature range. A surface diffusion mechanism is proposed to account for the nanobelts and nanoflakes growth. The Morin temperature T(M) of pure 1D alpha-Fe2O3 nanostructures is 121 K, which is far below their bulk counterparts. The coercive field depends on temperature, and takes values 471 Oe at 5 K and about 260 Oe when the temperature is greater than T(M), respectively.

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Source
http://dx.doi.org/10.1166/jnn.2013.5976DOI Listing

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