Remarkable Ag-carbenoid-initiated enone cyclopropanation-hydrolytic fragmentation-competitive 1,2-vs-1,4 addition reaction cascades were uncovered on a range of propargylic esters tethered to cyclohexadienones, leading to the highly efficient and stereospecific construction of densely functionalized bicyclo[3.3.1]nonanes under mild conditions.
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| http://dx.doi.org/10.1021/ol4006954 | DOI Listing |
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