AI Article Synopsis
- Eight homochiral metal-organic frameworks (MOFs) based on zinc (Zn) with a pore size of 1.2 nm were synthesized, featuring a unique zeolitic (unh) structure.
- These MOFs exhibit exceptional ability to regenerate when exposed to hydrolysis.
- A salt metathesis reaction performed on these three-dimensional MOFs in water transformed them into two-dimensional coordination polymers (CPs).
Article Abstract
Eight Zn-based porous (1.2 nm) homochiral MOFs (ValZnX, AlaZnX, X = Cl(-), Br(-), HCO2(-) and CH3CO2(-)) were synthesized which possess extremely rare zeolitic (unh) topology. These MOFs show an unprecedented hydrolytic regenerability. Salt metathesis reaction performed on these 3D MOFs in water resulted in 2D coordination polymers (CPs).
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| http://dx.doi.org/10.1039/c3cc41842a | DOI Listing |
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