2-Amino-5-bromo-pyridinium 5-chloro-2-hy-droxy-benzoate.

Acta Crystallogr Sect E Struct Rep Online

School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

Published: April 2013

In the 5-chloro-salicylate anion of the title salt, C5H6BrN2 (+)·C7H4ClO3 (-), an intra-molecular O-H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxyl-ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl-ate O atoms via a pair of N-H⋯O hydrogen bonds, forming an R 2 (2)(8) ring motif. The crystal structure also features N-H⋯O and weak C-H⋯O inter-actions, resulting in a layer parallel to the (10-1) plane.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629591PMC
http://dx.doi.org/10.1107/S160053681300665XDOI Listing

Publication Analysis

Top Keywords

2-amino-5-bromo-pyridinium 5-chloro-2-hy-droxy-benzoate
4
5-chloro-2-hy-droxy-benzoate 5-chloro-salicylate
4
5-chloro-salicylate anion
4
anion title
4
title salt
4
salt c5h6brn2
4
c5h6brn2 +·c7h4clo3
4
+·c7h4clo3 intra-molecular
4
intra-molecular o-h⋯o
4
o-h⋯o hydrogen
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!