[1,2-Bis(diisopropyl-phosphan-yl)ethane-κ(2) P,P'](carbonato-κ(2) O,O')nickel(II).

Acta Crystallogr Sect E Struct Rep Online

Facultad de Química, Universidad Nacional Autónoma de México, México DF, 04510, Mexico.

Published: April 2013

In the crystal of the title compound, [Ni(CO3)(C14H32P2)], the metal center in each of three independent mol-ecules shows slight tetra-hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P-Ni-P and cis-O-Ni-O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol-ecules. In the crystal, there are inter-molecular C-H⋯O hydrogen bonds that show a laminar growth in the ab plane.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629481PMC
http://dx.doi.org/10.1107/S1600536813006521DOI Listing

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