Mg-air oxygen shuttle batteries using a ZrO2-based oxide ion-conducting electrolyte.

Chem Commun (Camb)

Department of Automotive Science, Graduate School of Integrated Frontier Science, Kyushu University, 744 Motooka, Fukuoka, 819-0395, Japan.

Published: May 2013

A new concept of an "oxygen shuttle" type battery for Mg-air solid oxide batteries using a Ca-stabilized ZrO2 electrolyte was proposed and studied. The observed open circuit potential and discharge capacity were 1.81 V and 1154 mA h gMg(-1) (52% of the theoretical capacity), respectively.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c3cc40880aDOI Listing

Publication Analysis

Top Keywords

mg-air oxygen
4
oxygen shuttle
4
shuttle batteries
4
batteries zro2-based
4
zro2-based oxide
4
oxide ion-conducting
4
ion-conducting electrolyte
4
electrolyte concept
4
concept "oxygen
4
"oxygen shuttle"
4

Similar Publications

Mn Doping at High-Activity Octahedral Vacancies of γ-FeO for Oxygen Reduction Reaction Electrocatalysis in Metal-Air Batteries.

Angew Chem Int Ed Engl

December 2024

School of Materials Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin, 300072, P. R. China.

γ-FeO with the intrinsic cation vacancies is an ideal substrate for heteroatom doping into the highly active octahedral sites in spinel oxide catalysts. However, it is still a challenge to confirm the vacancy location of γ-FeO through experiments and obtain enhanced catalytic performance by preferential occupation of octahedral sites for heteroatom doping. Here, a Mn-doped γ-FeO incorporated with carbon nanotubes catalyst was developed to successfully achieve preferential doping into highly active octahedral sites by employing γ-FeO as the precursor.

View Article and Find Full Text PDF

Enhanced oxygen reduction activity of-MnOby NHplasma treatment.

Nanotechnology

April 2024

College of Materials Science and Engineering, Changsha University of Science & Technology, Changsha, 410000, People's Republic of China.

Oxygen vacancies and heteroatom doping play important role in oxygen reduction activity of metal oxides. Developing efficient modification method is one of the key issues in catalysts research. Room temperature plasma treatment, with the advantages of mild working conditions, no emissions and high efficiency, is a new catalyst modification method developed in recent years.

View Article and Find Full Text PDF

Pyridinic N-type doped at carbon has been known to have better electrocatalytic activity toward the oxygen reduction reaction (ORR) than the others. Herein, we proposed to prepare pyridinic N doped at carbon aerogels (CaA) derived from biomass, i.e.

View Article and Find Full Text PDF

Phosphorus recovery from sewage sludge via Mg-air battery system.

Sci Total Environ

May 2024

Shanghai Youlian Zhuyuan First Sewage Treatment Investment Development Co., Ltd, Shanghai 200125, China.

Article Synopsis
  • Phosphorus scarcity is a significant issue, and Mg-air batteries (MAB) have potential for recovering phosphorus as struvite through electrochemical reactions.
  • Variations in initial phosphorus concentration and reaction time greatly influence phosphorus recovery, electricity generation, and struvite production efficiency, with optimal conditions yielding high phosphorus removal and struvite purity.
  • Incorporating solid carbon sources from agricultural waste enhances phosphorus release and suggests that MAB may offer a sustainable method for recovering phosphorus from sewage sludge.
View Article and Find Full Text PDF

Flexible magnesium (Mg)-air batteries provide an ideal platform for developing efficient energy-storage devices toward wearable electronics and bio-integrated power sources. However, high-capacity bio-adaptable Mg-air batteries still face the challenges in low discharge potential and inefficient oxygen electrodes, with poor kinetics property toward oxygen reduction reaction (ORR). Herein, spinel nickel cobalt oxides (NiCoO) nanowires immobilized on nitrogen-doped TiCT (NiCoO/N-TiCT) are reported via surface chemical-bonded effect as oxygen electrodes, wherein surface-doped pyridinic-N-C and Co-pyridinic-N moieties accounted for efficient ORR owing to increased interlayer spacing and changed surrounding environment around Co metals in NiCoO.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!