A new concept of an "oxygen shuttle" type battery for Mg-air solid oxide batteries using a Ca-stabilized ZrO2 electrolyte was proposed and studied. The observed open circuit potential and discharge capacity were 1.81 V and 1154 mA h gMg(-1) (52% of the theoretical capacity), respectively.
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http://dx.doi.org/10.1039/c3cc40880a | DOI Listing |
Angew Chem Int Ed Engl
December 2024
School of Materials Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin, 300072, P. R. China.
γ-FeO with the intrinsic cation vacancies is an ideal substrate for heteroatom doping into the highly active octahedral sites in spinel oxide catalysts. However, it is still a challenge to confirm the vacancy location of γ-FeO through experiments and obtain enhanced catalytic performance by preferential occupation of octahedral sites for heteroatom doping. Here, a Mn-doped γ-FeO incorporated with carbon nanotubes catalyst was developed to successfully achieve preferential doping into highly active octahedral sites by employing γ-FeO as the precursor.
View Article and Find Full Text PDFNanotechnology
April 2024
College of Materials Science and Engineering, Changsha University of Science & Technology, Changsha, 410000, People's Republic of China.
Oxygen vacancies and heteroatom doping play important role in oxygen reduction activity of metal oxides. Developing efficient modification method is one of the key issues in catalysts research. Room temperature plasma treatment, with the advantages of mild working conditions, no emissions and high efficiency, is a new catalyst modification method developed in recent years.
View Article and Find Full Text PDFACS Omega
March 2024
Department of Chemical Engineering, Sepuluh Nopember Institute of Technology, Kampus ITS Sukolilo, Surabaya 60111, Indonesia.
Pyridinic N-type doped at carbon has been known to have better electrocatalytic activity toward the oxygen reduction reaction (ORR) than the others. Herein, we proposed to prepare pyridinic N doped at carbon aerogels (CaA) derived from biomass, i.e.
View Article and Find Full Text PDFSci Total Environ
May 2024
Shanghai Youlian Zhuyuan First Sewage Treatment Investment Development Co., Ltd, Shanghai 200125, China.
Small
August 2024
College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, 030006, China.
Flexible magnesium (Mg)-air batteries provide an ideal platform for developing efficient energy-storage devices toward wearable electronics and bio-integrated power sources. However, high-capacity bio-adaptable Mg-air batteries still face the challenges in low discharge potential and inefficient oxygen electrodes, with poor kinetics property toward oxygen reduction reaction (ORR). Herein, spinel nickel cobalt oxides (NiCoO) nanowires immobilized on nitrogen-doped TiCT (NiCoO/N-TiCT) are reported via surface chemical-bonded effect as oxygen electrodes, wherein surface-doped pyridinic-N-C and Co-pyridinic-N moieties accounted for efficient ORR owing to increased interlayer spacing and changed surrounding environment around Co metals in NiCoO.
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