AI Article Synopsis
- An aziridinyl stannatrane couples with aryl or alkenyl halides to create substituted aziridines.
- The reaction occurs under modified Stille conditions.
- It's efficient and can be done at room temperature using specific catalysts like ((t)Bu3P)2Pd and CuOP(O)Ph2.
Article Abstract
An aziridinyl stannatrane 8 couples with aryl or alkenyl halides RX under modified Stille conditions to afford substituted aziridines. Efficient coupling at room temperature is possible in the best examples in the presence of ((t)Bu3P)2Pd and CuOP(O)Ph2 (CuDPP).
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| http://dx.doi.org/10.1021/jo4005052 | DOI Listing |
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