We study the response of a spherical colloid under alternating electric fields (AC fields) by mesoscopic simulation method, accounting in full for hydrodynamic and electrostatic interactions. We focus on a special case of uncharged colloids. The main polarization mechanism is the "volume polarization", where ionic currents are deflected by the core of the uncharged colloid. Specifically, we compute the polarizability of a single colloid and systematically investigate the effect of AC field frequency and salt concentration. The simulation results are compared with predictions from classical Maxwell-Wagner theory and electrokinetic theory.
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http://dx.doi.org/10.1140/epje/i2013-13033-0 | DOI Listing |
Colloids Surf B Biointerfaces
October 2023
MDRCBB, Minnesota Dental Research Center for Biomaterials and Biomechanics, University of Minnesota, Minneapolis, MN 55455, USA; Division of Basic and Translational Research, Faculty of Odontology, UIC Barcelona - Universitat Internacional de Catalunya, Sant Cugat del Vallès 08195, Spain; Institute for Bioengineering of Catalonia (IBEC), Barcelona 08028, Spain. Electronic address:
Naso- and oropharyngeal swabs are the Center for Disease Control and Prevention (CDC) -recommended disease sampling methods for respiratory viruses. The short swabbing time for sampling by these methods may lead to variability in test results. Further, these methods are mildly invasive and can cause discomfort, tearing or gag reflexes in tested individuals.
View Article and Find Full Text PDFElectrophoresis
September 2024
Department of Mathematics, National Institute of Technology Durgapur, Durgapur, West Bengal, India.
This article deals with the electrophoresis of hydrophobic colloids absorbed by a layer of polymers with an exponential distribution of the polymer segments. The functional groups present in the polymer layer further follow the exponential distribution. We made an extensive mathematical study of the electrophoresis of such core-shell structured soft particles considering the combined impact of heterogeneity in polymer segment distribution, ion steric effect, and hydrodynamic slippage of the inner core.
View Article and Find Full Text PDFInt J Pharm
October 2024
Department of Medicinal Chemistry, Uppsala University, SE-75123 Uppsala, Sweden. Electronic address:
Subcutaneous (SC) injection is a common route of administration for drug compounds with poor oral bioavailability. However, bioavailability is often variable and incomplete, and there is as yet no standard accepted medium for simulation of the human SC environment. In this work we evaluate a FRAP based method for quantitative determination of local self-diffusion coefficients within extracellular matrix (ECM) mimetic hydrogels, potentially useful as in vitro models for drug transport in the ECM after SC injection.
View Article and Find Full Text PDFJ Phys Chem B
June 2024
Soft Matter, Fluidics and Interfaces, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands.
Diffusiophoresis is the movement of the colloidal particles in response to a concentration gradient and can be observed for both electrolyte (e.g., salt) and nonelectrolyte (e.
View Article and Find Full Text PDFJ Colloid Interface Sci
July 2024
Forschungszentrum Juelich, Biomacromolecular Systems and Processes (IBI-4), Wilhelm-Johnen-Strasse, 52428 Juelich, Germany; University of Twente, Computational Chemical Physics, PO Box 217, 7500 AE Enschede, the Netherlands. Electronic address: https://www.utwente.nl/en/tnw/ccp/.
Migration of colloidal particles induced by temperature gradients is commonly referred to as thermodiffusion, thermal diffusion, or the (Ludwig-)Soret effect. The thermophoretic force experienced by a colloidal particle that drives thermodiffusion consists of two distinct contributions: a contribution resulting from internal degrees of freedom of single colloidal particles, and a contribution due to the interactions between the colloids. We present an irreversible thermodynamics based theory for the latter collective contribution to the thermophoretic force.
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