The well-characterized ruthenium(II) biscarboxylate complex [Ru(O2CMes)2(p-cymene)] enabled versatile direct (hetero)arylations of C(sp(3))-H bonds with low (co)catalyst loading and ample substrate scope. Detailed mechanistic studies provided strong support for a facile and reversible C(sp(3))-H bond metalation.
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| http://dx.doi.org/10.1021/jo400658d | DOI Listing |
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