This report describes the synthesis, characterization, and magnetic properties of two novel phosphonate-based Co(II) cages. Structural investigation reveals some interesting geometrical features in the molecular core that may provide new models in single molecular magnetic materials.
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| http://dx.doi.org/10.1021/ic3025183 | DOI Listing |
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Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials.
Acc Chem Res
January 2025
College of Chemistry, Sichuan University, Chengdu 610065, P. R. China.
Article Synopsis
- The invention of lasers and inorganic second-order nonlinear optical (NLO) crystals has revolutionized technology by enabling unique frequency conversions, essential for various applications including information transmission and industrial uses.
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Phosphorescent metallaknots of Au(I)-bis(acetylide) strands directed by Cu(I) π-coordination.
Proc Natl Acad Sci U S A
September 2024
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
Knots containing metal atoms as part of their continuous strand backbone are termed as metallaknots. While several metallaknots have been synthesized through one-pot self-assembly, the designed synthesis of metallaknots by controlling the arrangement of entanglements and strands connectivity remains unexplored. Here, we report the synthesis of metallaknots composed with Au(I)-bis(acetylide) linkages and templated by Cu(I) ions.
View Article and Find Full Text PDFIntermolecular Anionic Mixed-Valence and π-Dimer Complexes of ortho-Pentannulated Bisazacoronene Diimide.
Angew Chem Int Ed Engl
January 2025
MOLTECH-Anjou, SFR MATRIX, Univ Angers, CNRS, 2 Bd Lavoisier, 49000, Angers, France.
This study reports the serendipitous discovery of intermolecular anionic mixed-valence (MV) and π-dimer species in ortho-pentannulated BisAzaCoroneneDiimides (BACDs) during their electrochemical reduction in a non-aqueous solvent. A library of nitrogen-containing extended PDIs was synthesized via an aza-benzannulation reaction followed by a Pd-catalysed ortho-pentannulation reaction. Ortho-pentannulated BACDs revealed strong aggregation abilities in solution.
View Article and Find Full Text PDFDiscovery and characterization of BRBV-sheep virus in nasal swabs from domestic sheep in China.
Front Cell Infect Microbiol
July 2024
College of Veterinary Medicine, Inner Mongolia Agricultural University, Hohhot, China.
Introduction: The escalating occurrence of infectious disease outbreaks in humans and animals necessitates innovative, effective, and integrated research to better comprehend their transmission and dynamics. Viral infection in livestock has led to profound economic losses globally. Pneumonia is the prevalent cause of death in sheep.
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