The composites based on plasticized starch and graphene oxide/reduced graphene oxide.

Carbohydr Polym

Chemistry Department, School of Science, Tianjin University, Tianjin 300072, China.

Published: April 2013

The graphite was oxidized to prepare graphene oxide (GO), and GO was reduced by glucose to obtain reduced graphene oxide (RGO) sheet. There were abundant and residual oxygen-containing groups on GO and RGO, respectively. Compared to graphite, the GO and RGO sheets appeared flat and transparent, and the aqueous suspensions followed the Lambert-Beer's law well. The composites were also fabricated by using GO and RGO as the filler in plasticized-starch (PS) matrix. Because of more oxygen-containing groups, GO could form the stronger interaction with PS matrix than RGO. And GO/PS composites exhibited better tensile strength, elongation at break and moisture barrier than RGO/PS composites, but lower thermal stability. GO/PS composites could protect against UV light, while the conductivities of RGO/PS composites could reach 1.07×10(-4), 6.92×10(-4) and 0.01 S/cm, respectively stored at RH50, 75 and 100%.

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http://dx.doi.org/10.1016/j.carbpol.2013.01.007DOI Listing

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