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http://dx.doi.org/10.1002/anie.201300531 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Sichuan University, School of Chemistry, 29 Wangjiang Road, 610064, Chengdu, CHINA.
Electrocatalytic transfer alkyne semi-hydrogenation with H2O as hydrogen source is industrially promising for selective electrosynthesis of high value-added alkenes while inhibiting byproduct alkanes. Although great achievements, their development has remarkably restricted by designing atomically sophisticated electrocatalysts. Here, we reported single-crystalline mesoporous copper nanoplates (meso-Cu PLs) as a robust yet highly efficient electrocatalyst for selective alkene electrosynthesis from transfer semi-hydrogenation reaction of alkyne in H2O.
View Article and Find Full Text PDFSmall
January 2025
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, School of Materials Science and Engineering, Hubei University, Wuhan, 430062, P. R. China.
Innovative design strategies of fog harvesting devices (FHDs) demonstrate promising remedy for water crisis in arid areas. 1D FHDs ensure unimpeded wind circulation and can be manufactured more cost-effectively for extensive regions. Inspired by cactus thorns, desert beetles, and spider silk, two metal organic frameworks (MOFs) functionalized Cu wires with opposite wettability are double-twisted by a mechanical twisting machine, forming 1D double-spiral Cu wires with alternating superhydrophobic/superhydrophilic dual-MOF patterns.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Laboratory of Advanced Optoelectronic Materials, Suzhou Key Laboratory of Novel Semiconductor-Optoelectronics Materials and Devices, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Circularly polarized luminescence (CPL) materials have drawn increasing attention for their potential applications in optical displays and chemo/biosensing. Nevertheless, the construction of circularly polarized room-temperature phosphorescence (CPRTP) materials is still a significant challenge. In this work, four liquid crystalline polymer network films with RTP properties have been fabricated via photopolymerization of cholesteric liquid-crystalline mixtures containing different amounts of commercially available dyes.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
State Key Lab for Hubei New Textile Materials and Advanced Processing Technology, College of Materials Science & Engineering, College of Textile Science & Engineering, Wuhan Textile University, 430200 Wuhan, China. Electronic address:
Cellulose nanofibers (CNFs) have gained increasing attention due to their robust mechanical properties, favorable biocompatibility, and facile surface modification. However, green and recyclable CNF production remains challenging. Herein, a green, low-cost and room-temperature strategy was developed to exfoliate CNFs using deep eutectic solvents.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Institute of Materials Research and Engineering, Sensor and Flexible Electronics, 2 Fusionopolis Way, 138634, SINGAPORE.
Radical covalent organic frameworks (RCOFs) have demonstrated significant potential in redox catalysis and energy conversion applications. However, the synthesis of stable RCOFs with well-defined neutral carbon radical centers is challenging due to the inherent radical instability, limited synthetic methods and characterization difficulties. Building upon the understanding of stable carbon radicals and structural modulations for preparing crystalline COFs, herein we report the synthesis of a crystalline carbon-centered RCOF through a facile post-oxidation process.
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