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Synthesis of 1,4-Diketones from Esters Enabled by a Tetraborylethane Reagent.
Org Lett
January 2025
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China.
A modular synthesis method for 1,4-diketones has been developed. Utilizing inexpensive carboxylic acid esters as carbonyl sources and tetraborylethane () as a nucleophilic reagent, a one-pot strategy for constructing two C-C bonds was established. Notably, this reaction proceeds without the involvement of transition metals and exhibits excellent functional group compatibility.
View Article and Find Full Text PDFWhat Is the Optimal Geometry of Dissolving Microneedle Arrays? A Literature Review.
Pharmaceutics
January 2025
Department of Pharmaceutical Technology and Biopharmacy, University of Groningen, 9713 AV Groningen, The Netherlands.
The application of dissolving microneedle arrays (DMNAs) is an emerging trend in drug and vaccine delivery as an alternative for hypodermic needles or other less convenient drug administration methods. The major benefits include, amongst others, that no trained healthcare personnel is required and that the recipient experiences hardly any pain during administration. However, for a successful drug or vaccine delivery from the DMNA, the microneedles should be inserted intact into the skin.
View Article and Find Full Text PDFDefensive Mechanisms of Likely Enhance Its Invasiveness as One of the World's Worst Alien Species.
Plants (Basel)
January 2025
Department of Applied Biological Science, Faculty of Agriculture, Kagawa University, Miki, Kita 761-0795, Kagawa, Japan.
Kunth is native to tropical America and has invaded tropical and subtropical Asia and numerous Pacific Islands. It forms dense thickets and reduces native species diversity and populations in its introduced range. This invasive vine also seriously impacts many agricultural crops and is listed as one of the world's 100 worst invasive alien species.
View Article and Find Full Text PDFGenetic Stability and Inbreeding in a Synthetic Maize Variety Based on a Finite Model.
Plants (Basel)
January 2025
Departamento de Fitotecnia, Instituto de Horticultura, Universidad Autónoma Chapingo, km 38.5 Carretera México-Texcoco, Chapingo 56230, Estado de México, Mexico.
A synthetic variety (SV) of maize may not become stable if the sample size representing each parental line (m) is small. This research aimed to evaluate the effect of m on the inbreeding coefficient (IC) of the SV (FSynL) and on the stability of its genetic constitution. An SV formed by randomly mating l unrelated lines whose inbreeding coefficient is F was considered, and a random sample was taken from the genotypic array of the progeny produced by selfing a parental line A1A2 (GA) This sample was visualized as a set of g groups of four plants whose genotypes are all four of the GA and e represented the number of plants that failed to form a group.
View Article and Find Full Text PDFFreeze-Drying for the Reduction of Fruit and Vegetable Chain Losses: A Sustainable Solution to Produce Potential Health-Promoting Food Applications.
Plants (Basel)
January 2025
Department of Agriculture, Forestry and Food Science, University of Torino, Largo Braccini 2, 10095 Grugliasco, Italy.
Freeze-drying fresh vegetables and fruits may not only prevent post-harvest losses but also provide a concentrated source of nutrients and phytochemicals. This study focused on the phenolic composition of different freeze-dried products derived from horticultural crop remains (HCRs) in the vegetable and fruit production chain. These products may be considered as a potential health-promoting solution for preventing post-harvest fruit spoiling and losses.
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