Powders of Y2O3 co-doped with Yb3+ and Er3+ composed of well-crystallized nanoparticles (30 to 50 nm in diameter) with no adsorbed ligand species on their surface are prepared by polymer complex solution method. These powders exhibit up-conversion emission upon 978-nm excitation with a color that can be tuned from green to red by changing the Yb3+/Er3+ concentration ratio. The mechanism underlying up-conversion color changes is presented along with material structural and optical properties. PACS: 42.70.-a, 78.55.Hx, 78.60.-b.
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http://dx.doi.org/10.1186/1556-276X-8-131 | DOI Listing |
Molecules
January 2025
College of Chemistry and Chemical Engineering, Central South University, Changsha 410017, China.
Ratiometric lanthanide coordination polymers (Ln-CPs) are advanced materials that combine the unique optical properties of lanthanide ions (e.g., Eu, Tb, Ce) with the structural flexibility and tunability of coordination polymers.
View Article and Find Full Text PDFRSC Adv
January 2025
Department of Condensed Matter Physics, GdS Optronlab, LUCIA Building, University of Valladolid Paseo de Belén 19 47011 Valladolid Spain.
Luminescent materials doped with rare-earth (RE) ions have emerged as powerful tools in thermometry, offering high sensitivity and accuracy. However, challenges remain, particularly in maintaining efficient luminescence at elevated temperatures. This study investigates the thermometric properties of BiVO: Yb/Er (BVO: Er/Yb) nanophosphors synthesized the sol-gel method.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
Suzhou Laboratory, Suzhou, Jiangsu, China.
Fucoxanthin is a typical carotenoid that absorbs light in the blue region of the visible spectrum, and its detailed electronic structures remain to be clarified. It is well known that carotenoids harvest energy from sunlight and transfer it to chlorophylls (Chls) and/or bacteriochlorophylls (BChls) through its excited states as the intermediate states; however, some excited states still need evidence to be definitely confirmed. Through steady-state fluorescence emission spectroscopy and femtosecond time-resolved fluorescence up-conversion technique, we provide new evidence for the identification of the excited S state in fucoxanthin, a representative of carotenoids.
View Article and Find Full Text PDFJ Fluoresc
November 2024
Department of Physics and Photonics Science, National Institute of Technology, Hamirpur, 177005, H.P, India.
Luminescence
November 2024
Department of Physics, Sri Venkateswara University, Tirupati, India.
Er and Er/Yb-doped phosphate-based glasses have been synthesized by melt quenching technique and are characterized by absorption spectra, infrared emission, decay curves, Fourier transform infrared spectrum and up-conversion studies. From the absorption spectra, intensity parameters and radiative properties have been derived utilizing the Judd-Ofelt theory. Er-doped glass is found to have larger radiative lifetime for the laser originating from I level at 1537 nm.
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