This study describes the yeast Rhodotorula mucilaginosa strain LM9 isolated from copper-bearing, organic-rich Kupferschiefer black shale and its role in copper biotransformation. Strain LM9 exhibited great ability to simultaneously mobilize and immobilize copper from this sedimentary rock. In addition, it showed considerable resistance to copper and high uptake of this metal. Moreover, malic and oxalic acid as well as siderophore (rhodotorulic acid) produced by this strain enhanced its resistance by promoting the mobilization and complexation of copper from black shale. These processes, characterized here under laboratory conditions, are assumed to play a role in copper cycling in black shale as well as in the adaptation of strain LM9 to the conditions prevailing in its natural mine habitat. The findings of this study indicate that yeast strain LM9 might be used for the recovery of copper particularly from alkaline or slightly neutral ores in a non-chemical environmentally-friendly procedure.
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http://dx.doi.org/10.1016/j.chemosphere.2013.02.022 | DOI Listing |
Bull Environ Contam Toxicol
January 2025
Key Laboratory of Surficial Geochemistry, Ministry of Education School of Earth Sciences and Engineering, Nanjing University, Nanjing, 210023, China.
Heavy metals were analyzed in rhizosphere soils and rice grains collected from typical black shale areas. The concentrations of As, Cd, Cu, and Zn in the rhizosphere soil exceeded the current soil environmental quality standards. Cd exhibited the highest bioaccumulation capacity, with 45% of rice grains exceeding food safety limit.
View Article and Find Full Text PDFACS Omega
January 2025
Hubei Key Laboratory of Petroleum Geochemistry and Environment, College of Resources and Environment, Yangtze University, Wuhan 430100, China.
Recently, significant breakthroughs have been made in the exploration of shale gas in the Lower Cambrian black shale of the Sichuan Basin, indicating a promising commercial extraction potential. However, there remains considerable controversy regarding the pore structural characteristics for this shale formation, especially in the deep-water region. To address this, this paper focused on core samples from two shale gas wells (Xa1 and Xb1) located in the slope-basin facies zone during the Early Cambrian.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Civil Engineering, Southwest Jiaotong University, Chengdu, Sichuan Province 610031, China.
Chemical weathering of lithologies with high geochemical backgrounds such as black shale has been proposed to be a critical source for toxic elements in soil and water systems. However, mechanisms controlling the release, migration and enrichment of toxic elements during black shale weathering are poorly understood. This study utilized a suite of micro analytical techniques such as TESCAN integrated mineral analyzer (TIMA), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), X-ray photoelectron spectroscopy (XPS) and electron micro-probe analysis (EMPA) to elucidate the intimate relationship between mineralogical transformations and elemental behaviors from profile scale to mineral scale.
View Article and Find Full Text PDFSci Rep
November 2024
State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an, 710069, Shaanxi, China.
The tectonic of the Middle and Late Ordovician in the western margin of the north China Platform is complex, and the accumulation models of organic matter of the Wulalike Formation formed during this period are still unclear. Total organic carbon (TOC) content, mineral composition, organic carbon isotope composition, as well as the major and trace elements in the shale samples were all measured in this study. The Wulalike Formation was formed during a tectonic transition from a passive continental margin to an active continental margin.
View Article and Find Full Text PDFSci Total Environ
December 2024
School of Geosciences, Yangtze University, Wuhan 430100, China.
Following the NOE, the early Cambrian witnessed the global deposition of marine black shales with high U concentrations. This study analyzes the Lower Cambrian Yuertusi Formation in the Tarim Basin, China, focusing on U isotopes to elucidate U enrichment mechanisms in black shales and their potential for helium generation. In wells XK-1, LT-1, and LT-3, the average U concentrations in the Yuertusi Formation black shale are 41.
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