AI Article Synopsis
- The study presents the creation and evaluation of new gold amide complexes, both mononuclear and dinuclear, numbered 1-7.
- Dinuclear complexes 6b and 7 were analyzed using single crystal X-ray analysis for detailed characterization.
- The research included solution NMR and freezing point depression experiments to understand the complexes' behavior in solution and investigate the de-ligation process relevant to gold catalysis.
Article Abstract
We report the synthesis and activity of new mononuclear and dinuclear gold amide complexes 1-7. The dinuclear complexes 6b and 7 were characterised by single crystal X-ray analysis. We also report solution NMR and freezing point depression experiments to rationalise their behaviour in solution and question the de-ligation process invoked in gold catalysis.
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| http://dx.doi.org/10.1039/c3dt33039g | DOI Listing |
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